水泥基材料的溶蚀劣化研究进展与评述

    Research progress and review on corrosion and degradation of cement-based materials

    • 摘要: 溶蚀是水泥基材料与软水长期接触而引起水泥石脱钙造成微结构劣化和宏观性能降低的一种化学腐蚀,已成为水泥基材料最常见的劣化问题之一。简述了国内外水泥基材料溶蚀研究现状,重点论述了溶蚀特性,并讨论了其劣化过程和介绍了相关溶蚀模型;同时,特别指出了目前溶蚀研究中小孔对溶蚀进程的影响、粉煤灰抗溶蚀临界掺量、C-S-H脱钙起点等争议性问题,并对相关问题提出了个人见解。此外归纳了溶蚀劣化机理、基础研究理论、表征参数间的定量关系以及掺合物临界掺量等有待进一步研究的问题,以为有志于溶蚀研究的学者提供科研方向。

       

      Abstract: Chemical corrosion of cement-based materials, caused by its contacting with soft water for long-term, can induce cement decalcification, which may cause micro structure and macro performance deterioration, becoming one of the most common cement-based material degradation problems. In this paper, the researches on dissolution of cement-based materials at home and abroad are reviewed, the characteristics and the degradation progress of corrosion are discussed, and some corrosion models are introduced. Particularly, the effect of small pores on corrosion process, corrosion -resistant critical content of fly ash, the starting point of C-S-H decalcification and other controversial issues in present corrosion researches are pointed out, and personal opinion for related problems is put forward. In addition, the further research issues such as corrosion degradation mechanism, basic research theory, the quantitative relationship between parameters and the critical content of admixture are summarized, which can provide scientific research direction for the scholars.

       

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