长江陆溪口鹅头洲土壤重金属空间分布及源解析

    Spatial distribution and source identification of heavy metals in soil at Luxikou goose-head braided channel of Changjiang River

    • 摘要: 长江中游陆溪口鹅头洲隶属于国家级自然保护区,为查明其土壤重金属分布及污染来源情况,服务地区生态环境和物种保护,采集了汛期淹水前后表层(0~20 cm)及深层(50~200 cm)土壤样品共43份,分析了土壤As、Cd、Cr、Cu、Hg、Ni、Pb、Zn含量与空间分布特征,开展重金属风险评价,并利用主成分分析和PMF模型分析重金属来源。结果表明:①表层土壤重金属元素含量与湖北省背景值比值为Cd>Cu>Pb>Zn>Hg>Ni>Cr>As,且表层土壤各元素含量高于深层。②空间分布上,洲体土壤重金属元素相对集中于中洲洲头中部及新洲洲尾滨江处,富集于地表,向内陆迁移,汛期淹水后重金属元素含量近河道处减少,近洲心处增加。③地累积指数Igeo和潜在生态风险评价结果表明,Cd表现为中度污染(Igeo均值1.26)及较强潜在生态风险(Eri均值116.32),Hg处于中度风险(Eri均值52.77),其余元素多为无污染及低风险。④基于主成分和PMF源解析,土壤Pb的自然地质背景及河道交通运输双重来源的贡献占比相当,Hg主要来自交通运输船只燃油燃烧排放,其余重金属元素主要来自自然地质背景。陆溪口鹅头洲重金属主要来自自然地质背景和航道交通运输,其贡献占比分别为74.56%和25.44%,可加强监督航道船只燃油使用与管理,以进一步保护地区物种与长江生态安全。

       

      Abstract: The Luxikou goose-head braided channel in middle reaches of the Changjiang River is situated in national nature reserve.In order to identify the spatial distribution and sources of heavy metals in the soil, and to serve the regional ecological environment and species protection, 43 soil samples were collected to analyze the contents and spatial distribution characteristics of heavy metals (As, Cd, Cr, Cu, Hg, Ni, Pb, Zn), including topsoil (0~20 cm) and subsoil (50~200 cm) in Luxikou braided channel before and after flooding.Heavy metal risk was evaluated and the sources were analyzed by principal component analysis and PMF model.The results showed that: ① the ratio of heavy metal elements in surface soil to the background value of Hubei Province followed the order Cd > Cu > Pb > Zn > Hg > Ni > Cr > As, and the concentrations in topsoil were higher than those in subsoils.② On spatial distribution, the soil heavy metal elements in the zone were concentrated in the middle of the head of Zhongzhou and the tail of Xinzhou.The metals were deposited on the surface, and migrated towards the center of the zone.After flooding, heavy metal concentrations near the river channel decreased, while it increased near the center of the zone.③ According to geo-accumulation index and potential ecological risk index, Cd was classified as moderately polluted (The average of Igeo was 1.26) and at strong potential ecological risk (The average of Eri was 116.32), Hg was at moderate risk (The average of Eri was 52.77), while the remaining elements were mostly unpolluted and posed a low potential risk.④ Based on principal component and PMF source analysis, Pb originated from both natural geological background and river transportation with roughly equal contribution, while Hg primarily came from shipping fuel combustion emissions.The others mainly originated from natural geological backgrounds.The soil heavy metals in Luxikou goose-head braided channel mainly come from the natural geological background and waterway transportation, and their contributions accounted for 74.56% and 25.44%, respectively.Supervision of the use and management of fuel oil by vessels in the waterway can be strengthened to further protect regional species and the ecological security of the Changjiang River.

       

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