1998~2023年长江流域地表水体总磷浓度变化趋势及驱动因素

    Variation trend and driving factors of total phosphorus concentration in surface water of Changjiang River Basin from 1998 to 2023

    • 摘要: 总磷是长江流域备受关注的首要超标污染物,对长江流域水生态具有重要影响。分析了1998~2023年长江干流、主要支流及湖库总磷浓度和变化趋势。结果表明:①长江干流总磷浓度从金沙江起点至长江口沿程总体呈上升趋势,但都低于河流总磷Ⅲ类标准限值(0.20 mg/L)。长江干流宜宾至三峡大坝江段,总体上丰水期总磷高于枯水期,而长江口水域枯水期总磷高于丰水期。②近20 a来,长江干流尤其是宜宾至洞庭湖出口江段磷的赋存形态发生了显著变化,宜宾至清溪场江段的磷在丰水期以颗粒态为主,在平、枯水期则以溶解态为主, 清溪场至洞庭湖出口在各水期皆以溶解态为主;武汉至徐六泾江段颗粒态磷略高于溶解态磷;长江口水域在各水期皆以颗粒态为主。③近10 a来,长江干流和大部分主要支流总磷浓度出现了系统性下降趋势,其主要驱动力是水污染控制和“三磷”治理。相对于高值年份,2021~2023年长江干流CP(澄清样总磷)、TP(原样总磷)和DP(溶解态磷)下降比例皆超50%。岷江、沱江、嘉陵江、乌江CP浓度下降比例分别为68.9%,59.2%,66.7%,92.6%。④长江流域84%的湖泊总磷全年性或季节性超过Ⅲ类标准限值。大部分湖泊总磷偏高仍是长江流域水生态环境关键问题之一,流域内水库总磷浓度超标情况远小于湖泊。

       

      Abstract: Total phosphorus(TP) in the Changjiang River Basin is the primary standard-exceeding pollutant that has attracted much attention, and it has a significant influence on the aquatic ecology.The concentrations and changing trends of TP in the Changjiang River Basin′s main stream, key tributaries, lakes, and reservoirs are studied from 1998 to 2023.The results show that: ① The TP concentration in the main stream of the Changjiang River shows an overall increasing trend from the source of the Jinsha River to the Yangtze River Estuary, but TP concentrations in all reaches are below the Class Ⅲ standard limit of 0.20 mg/L.In the section of the Changjiang River main stream from Yibin to the Three Gorges Dam, the TP concentration is generally higher during the wet season than during the dry season.In contrast, the concentration in the Yangtze River Estuary area is higher during the dry season than during the wet season.② Over the past two decades, the phosphorus speciation in the main stream of the Changjiang River, particularly in the stretch from Yibin to the outlet of Dongting Lake, has undergone significant changes.This shift has primarily been driven by a substantial reduction in sediment load in the main stem, resulting from the operation of the Three Gorges Reservoir and the cascade reservoirs in the lower Jinsha River, as well as soil and water processes across the basin.The current speciation characteristics are as follows: in the section from Yibin to Qingxichang, phosphorus is predominantly in particulate form during the wet season, while dissolved forms dominate during normal and dry seasons.From Qingxichang to the outlet of Dongting Lake, dissolved phosphorus is the main form across all hydrological periods.In the stretch from Wuhan to Xuliujing, particulate phosphorus is slightly higher than dissolved phosphorus.In the Yangtze River Estuary, particulate phosphorus remains the dominant form throughout all hydrological periods.③ Over the past decade, the TP concentration in the main stream of the Changjiang River and most of its major tributaries has shown a systematic decline, primarily driven by water pollution control and the management of "three phosphorus" sources.Compared to peak concentration years, the concentrations of CP (clarified sample total phosphorus), TP (original sample total phosphorus), and DP (dissolved phosphorus) in the main stream of the Changjiang River have all decreased by more than 50% during 2021~2023.The reduction rates of CP concentration in some major tributaries are as follows: Minjiang River 68.9%, Tuojiang River 59.2%, Jialing River 66.7%, and Wujiang River 92.6%.④ In the Changjiang River Basin, 84% of the lakes have TP levels exceeding the Class Ⅲ water quality standard limit either year-round or seasonally.Elevated TP remains one of the key ecological and environmental issues for most lakes in the basin.In contrast, the incidence of TP exceeding standards in reservoirs across the basin is significantly lower than that in lakes.

       

    /

    返回文章
    返回