无溶剂环氧树脂涂层的制备与耐紫外老化性能评价

    Preparation of solvent-free epoxy resin coating and UV aging resistance evaluation

    • 摘要: 针对高寒高海拔地区水工混凝土表面环氧树脂防护涂层耐老化性能缺乏系统科学评价的问题,制备了CW无溶剂环氧树脂涂层,并采用紫外-冷凝加速老化试验,结合拉伸强度测试、FTIR光谱、DMA分析和显微形貌表征,探究了涂层老化机理与性能演变规律;此外选择厚度保持率和羰基峰面积比值作为失效指标,构建了耐紫外老化寿命预测模型进行寿命预测。结果表明:老化试验过程中环氧树脂涂层发生降解,导致表面出现黄变、粉化及孔洞等缺陷;前期化学键断裂导致涂层拉伸强度和玻璃化转变温度(Tg)降低;后期交联密度增加,拉伸强度和Tg回升,羰基特征峰面积也显著扩大;涂层在西藏日喀则和拉萨地区的使用寿命约为武汉地区的49%~54%。研究成果可为严苛复杂环境下水利水电工程防护修复材料的性能优化和工程应用提供参考。

       

      Abstract: In view of the lack of systematic and scientific evaluation on the aging resistance of epoxy resin protective coatings for hydraulic concrete in high-cold and high-altitude regions, this study prepared a solvent-free CW epoxy coating. An ultraviolet-condensation accelerated aging test was conducted, combined with tensile tests, FTIR spectroscopy, DMA analysis, and microscopic morphological characterization, to investigate the aging mechanism and performance evolution of the coating. Furthermore, the thickness retention rate and the carbonyl peak area ratio were selected as failure indicators to establish a life-prediction model for analyzing UV aging resistance. The results show that the epoxy coating degraded during aging, exhibiting surface defects such as yellowing, powdering, and pinholes. In the early stage, the breaking of chemical bonds led to a decrease in tensile strength and glass-transition temperature (Tg). In the later stage, the cross-linking density increased, resulting in the recovery of tensile strength and Tg, while the area of the carbonyl characteristic peak also expanded significantly. The service life of the coating in Shigatse and Lhasa was approximately 49%~54% of that in Wuhan. These findings can provide a reference for performance optimization and engineering application of protective and repair materials for water-conservancy and hydropower projects in harsh and complex environments.

       

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